I used POR-15 extensively on my XJ, due to New York winter rust. I had great luck with it sticking to rust, paint, and bare metal. The entire underside and interior ended up coated in it.
Brush application works ok, a roller is a little easier. If you decide to spray, wear a mask. That stuff outgassing on the interior took weeks and was beyond anything I expected in the odor department. Zero chance of driving with windows up.
Also, regardless of how well you prep and think you can "not touch the wet parts", you will. POR-15 is pretty thin if I remember right, and it got EVERYWHERE. Expect 3x more mess than with anything else you've ever used.
As others noted, VERY glossy. If you don't like gloss, plan on rattlecan jobs over the top.